Recently, researchers have shown great interest in compounds such as triflate and enotriflate that are synthesized by Comins reagent. For the above-mentioned reason, we planned to review the works related to organic synthesis using Comins reagent. So this review includes a whole new investigation of the Comins reagent which is used for stereoselective conversion of α–keto ester, enolate to enol triflate of lactone and vinyl triflate to methyl ketone. Comins reagent plays an important role in regioselectivity such as transformations of ketone or dienolates into vinyl triflates and it has a major application in highly selective oxidation in an easy and environmentally friendly manner.

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摘要

最近，研究人员对用Comins试剂合成的三氟甲磺酸和依诺氟甲磺酸等化合物表现出极大的兴趣。基于上述原因，我们计划回顾与使用 Comins 试剂的有机合成相关的工作。因此，本综述包括对用于将 α-酮酯、烯醇化物立体选择性转化为内酯的三氟甲磺酸烯醇以及将三氟甲磺酸乙烯酯转化为甲基酮的 Comins 试剂的全新研究。Comins试剂在区域选择性中起着重要作用，例如将酮或二烯醇化物转化为乙烯基三氟甲磺酸酯，它在以简单和环保的方式进行高选择性氧化方面具有重要应用。