合成环糊精基材料作为常见水污染物有效吸附剂的研究进展:综述,Journal of Environmental Chemical Engineering

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合成环糊精基材料作为常见水污染物有效吸附剂的研究进展:综述,Journal of Environmental Chemical Engineering

#合成环糊精基材料作为常见水污染物有效吸附剂的研究进展:综述,Journal of Environmental Chemical Engineering| 来源: 网络整理| 查看: 265

最近,基于环糊精(CD)的吸附剂由于其吸附动力学快、易于再生和机械稳定性高等优异性能而在水污染物去除方面受到了极大的关注。本综述系统地介绍了目前制备环糊精基吸附剂的方法,包括交联、固定化(接枝)、自组装、分子印迹和离子印迹。还讨论了使用 FTIR、 SEM 和 BET 分析对基于 CD 的吸附剂进行表征。此外,使用基于 CD 的吸附剂吸附特定污染物,如重金属、染料、内分泌干扰化学品、药物和其他有机污染物, 通过介绍吸附特性和机制来强调。与天然环糊精相比,改性环糊精促进了吸附剂与水相的分离,从而增强了基于环糊精的吸附剂在实际应用中的应用。大多数报道的基于 CD 的吸附剂对不同污染物的吸附表现出高效率。此外,CD 的内部疏水腔主要有助于捕获有机污染物,尤其是干扰内分泌的化学物质。交联和固定化的 CD 基吸附剂在同时去除混合污染物方面的性能非常出色。大多数基于 CD 的吸附剂可以使用合适的解吸洗脱液轻松再生。介绍了与基于 CD 的吸附剂相关的挑战和局限性,

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Progress of synthetic cyclodextrins-based materials as effective adsorbents of the common water pollutants: Comprehensive review

Recently, cyclodextrin (CD)-based adsorbents have received significant attention for water-pollutant removal owing to their excellent properties, such as rapid adsorption kinetics, easy regeneration, and high mechanical stability. This review systematically covers the current methods for preparing CD-based adsorbents, including crosslinking, immobilization (grafting), self-assembly, molecular imprinting, and ionic imprinting. The characterization of CD-based adsorbents using FTIR, SEM, and BET analysis is also discussed. Furthermore, the use of CD-based adsorbents for the adsorption of specific pollutants, such as heavy metals, dyes, endocrine-disrupting chemicals, pharmaceuticals, and other organic pollutants, is highlighted by introducing the adsorption properties and mechanisms. Compared with native cyclodextrins, modified cyclodextrins facilitate the separation of the adsorbent from the aqueous phase, thus enhancing the application of CD-based adsorbents in practical applications. Most of the reported CD-based adsorbents demonstrate high efficiency for the adsorption of different pollutants. Moreover, the interior hydrophobic cavity of CDs predominantly contributes to capturing organic pollutants, particularly endocrine-disrupting chemicals. The performance of crosslinked and immobilized CD-based adsorbents for the simultaneous removal of mixed pollutants is excellent. Most CD-based adsorbents can be easily regenerated using a suitable desorption eluent. The challenges and limitations associated with CD-based adsorbents are presented, along with possible solutions and developments for highly efficient CD-based adsorbents that can be applied in practical wastewater treatment.



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