从镁铝氧化物中去除锑酸根离子并同时形成类菱沸石的化合物,Separation and Purification Technology

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从镁铝氧化物中去除锑酸根离子并同时形成类菱沸石的化合物,Separation and Purification Technology

2024-07-11 06:19| 来源: 网络整理| 查看: 265

发现通过热分解Mg-Al层状双氢氧化物(Mg-Al LDH)获得的镁-铝氧化物(Mg-Al氧化物)被去除 锑(哦)6--(Sb(V))由于复水而在溶液中,并与Sb(V)结合形成类勃兰石的结构。尽管随着Mg-Al氧化物含量的增加,Sb的浓度降低,但是Mg / Al摩尔比的差异对该关系影响很小。高电荷密度的共存阴离子可部分防止Mg–Al氧化物去除溶液中的Sb(V)(所以42-- 和 一氧化碳32--)。在这种情况下,Mg-Al氧化物可能会再水化,并与溶液中的Sb(V)竞争性结合以构建类硼锌矿结构或与阴离子重构LDH结构。然而,在具有低电荷密度(CL共存阴离子的情况下-和OH - ),镁-铝氧化物可能再水合和优先结合的Sb(V)在溶液中以构建brandholzite状结构。氯高浓度的-和所以42-- 对Sb浓度的降低影响很小,而高浓度的 一氧化碳32-- 产生了很大的影响。

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Removal of antimonate ions and simultaneous formation of a brandholzite-like compound from magnesium–aluminum oxide

Magnesium–aluminum oxide (Mg–Al oxide), obtained by thermal decomposition of a Mg–Al layered double hydroxide (Mg–Al LDH), was found to remove Sb(OH)6- (Sb(V)) in solution because of rehydration, and to combine with Sb(V) to form a brandholzite-like structure. Although the Sb concentration decreased with increasing amounts of Mg–Al oxide, differences in the Mg/Al molar ratio had little effect on this relationship. The removal of Sb(V) in solution by Mg–Al oxide was partially prevented by coexistent anions with high charge densities (SO42- and CO32-). In this case, Mg–Al oxide likely rehydrates and competitively combines with Sb(V) in solution to construct a brandholzite-like structure or with anions to reconstruct the LDH structure. However, in the case of coexistent anions with low charge densities (Cl− and OH−), Mg–Al oxide likely rehydrates and preferentially combines with Sb(V) in solution to construct the brandholzite-like structure. A high concentration of Cl− and SO42- had little effect on the decrease in Sb concentration, whereas a high concentration of CO32- had a large effect.



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