三乙胺盐酸盐的理化性质及危险特性(SDS\MSDS)表 |
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三乙胺盐酸盐的理化性质及危险特性(SDS\MSDS)表
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1.Identification 1.1 GHS Product identifier Product name Triethylamine hydrochloride 1.2 Other means of identification Product number - Other names Ethanamine, N,N-diethyl-, hydrochloride 1.3 Recommended use of the chemical and restrictions on use Identified uses For industry use only. Uses advised against no data available 1.4 Supplier's details 1.5 Emergency phone number Emergency phone number - Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours). 2.Hazard identification 2.1 Classification of the substance or mixture Skin corrosion, Category 1B 2.2 GHS label elements, including precautionary statements Pictogram(s) Signal word Danger Hazard statement(s)H314 Causes severe skin burns and eye damage Precautionary statement(s) PreventionP260 Do not breathe dust/fume/gas/mist/vapours/spray. P264 Wash ... thoroughly after handling. P280 Wear protective gloves/protective clothing/eye protection/face protection. ResponseP301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water [or shower]. P363 Wash contaminated clothing before reuse. P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P310 Immediately call a POISON CENTER/doctor/… P321 Specific treatment (see ... on this label). P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. StorageP405 Store locked up. DisposalP501 Dispose of contents/container to ... 2.3 Other hazards which do not result in classificationnone 3.Composition/information on ingredients 3.1 Substances Chemical name Common names and synonyms CAS number EC number Concentration Triethylamine hydrochloride Triethylamine hydrochloride 554-68-7 none 100% 4.First-aid measures 4.1 Description of necessary first-aid measures General adviceConsult a physician. Show this safety data sheet to the doctor in attendance. If inhaledIf breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician. In case of skin contactWash off with soap and plenty of water. Consult a physician. In case of eye contactRinse thoroughly with plenty of water for at least 15 minutes and consult a physician. If swallowedNever give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician. 4.2 Most important symptoms/effects, acute and delayedno data available 4.3 Indication of immediate medical attention and special treatment needed, if necessaryno data available 5.Fire-fighting measures 5.1 Extinguishing media Suitable extinguishing mediaUse water spray, alcohol-resistant foam, dry chemical or carbon dioxide. 5.2 Specific hazards arising from the chemicalno data available 5.3 Special protective actions for fire-fightersWear self-contained breathing apparatus for firefighting if necessary. 6.Accidental release measures 6.1 Personal precautions, protective equipment and emergency proceduresUse personal protective equipment. Avoid dust formation. Avoid breathing vapours, mist or gas. Ensure adequate ventilation. Evacuate personnel to safe areas. Avoid breathing dust. For personal protection see section 8. 6.2 Environmental precautionsPrevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided. 6.3 Methods and materials for containment and cleaning upPick up and arrange disposal. Sweep up and shovel. Keep in suitable, closed containers for disposal. 7.Handling and storage 7.1 Precautions for safe handlingAvoid contact with skin and eyes. Avoid formation of dust and aerosols. Avoid exposure - obtain special instructions before use.Provide appropriate exhaust ventilation at places where dust is formed. For precautions see section 2.2. 7.2 Conditions for safe storage, including any incompatibilitiesStore in cool place. Keep container tightly closed in a dry and well-ventilated place. 8.Exposure controls/personal protection 8.1 Control parameters Occupational Exposure limit valuesno data available Biological limit valuesno data available 8.2 Appropriate engineering controlsHandle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday. 8.3 Individual protection measures, such as personal protective equipment (PPE) Eye/face protectionSafety glasses with side-shields conforming to EN166. Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Skin protectionWear impervious clothing. The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique(without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it. Respiratory protectionWear dust mask when handling large quantities. Thermal hazardsno data available 9.Physical and chemical properties Physical state hexagonal crystals from alcohol. Colour no data available Odour no data available Melting point/ freezing point -35°C(lit.) Boiling point or initial boiling point and boiling range 163°C Flammability no data available Lower and upper explosion limit / flammability limit no data available Flash point 65°C(lit.) Auto-ignition temperature no data available Decomposition temperature no data available pH no data available Kinematic viscosity no data available Solubility In water:1440 g/L (20 oC) Partition coefficient n-octanol/water (log value) no data available Vapour pressure no data available Density and/or relative density 0.75g/cm3 Relative vapour density no data available Particle characteristics no data available 10.Stability and reactivity 10.1 Reactivityno data available 10.2 Chemical stabilityStable under recommended storage conditions. 10.3 Possibility of hazardous reactionsno data available 10.4 Conditions to avoidno data available 10.5 Incompatible materialsno data available 10.6 Hazardous decomposition productsno data available 11.Toxicological information Acute toxicity Oral: no data available Inhalation: no data available Dermal: no data available Skin corrosion/irritationno data available Serious eye damage/irritationno data available Respiratory or skin sensitizationno data available Germ cell mutagenicityno data available Carcinogenicityno data available Reproductive toxicityno data available STOT-single exposureno data available STOT-repeated exposureno data available Aspiration hazardno data available 12.Ecological information 12.1 Toxicity Toxicity to fish: no data available Toxicity to daphnia and other aquatic invertebrates: no data available Toxicity to algae: no data available Toxicity to microorganisms: no data available 12.2 Persistence and degradabilityno data available 12.3 Bioaccumulative potentialno data available 12.4 Mobility in soilno data available 12.5 Other adverse effectsno data available 13.Disposal considerations 13.1 Disposal methods ProductThe material can be disposed of by removal to a licensed chemical destruction plant or by controlled incineration with flue gas scrubbing. Do not contaminate water, foodstuffs, feed or seed by storage or disposal. Do not discharge to sewer systems. Contaminated packagingContainers can be triply rinsed (or equivalent) and offered for recycling or reconditioning. Alternatively, the packaging can be punctured to make it unusable for other purposes and then be disposed of in a sanitary landfill. Controlled incineration with flue gas scrubbing is possible for combustible packaging materials. 14.Transport information 14.1 UN Number ADR/RID: Not dangerous goods. IMDG: Not dangerous goods. IATA: Not dangerous goods. 14.2 UN Proper Shipping Name ADR/RID: unknown IMDG: unknown IATA: unknown 14.3 Transport hazard class(es) ADR/RID: Not dangerous goods. IMDG: Not dangerous goods. IATA: Not dangerous goods. 14.4 Packing group, if applicable ADR/RID: Not dangerous goods. IMDG: Not dangerous goods. IATA: Not dangerous goods. 14.5 Environmental hazards ADR/RID: no IMDG: no IATA: no 14.6 Special precautions for userno data available 14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Codeno data available 15.Regulatory information 15.1 Safety, health and environmental regulations specific for the product in question Chemical name Common names and synonyms CAS number EC number Triethylamine hydrochloride Triethylamine hydrochloride 554-68-7 none European Inventory of Existing Commercial Chemical Substances (EINECS) Listed. EC Inventory Listed. United States Toxic Substances Control Act (TSCA) Inventory Listed. China Catalog of Hazardous chemicals 2015 Not Listed. New Zealand Inventory of Chemicals (NZIoC) Listed. Philippines Inventory of Chemicals and Chemical Substances (PICCS) Listed. Vietnam National Chemical Inventory Not Listed. Chinese Chemical Inventory of Existing Chemical Substances (China IECSC) Listed. 16.Other information Information on revision Creation Date Aug 12, 2017 Revision Date Aug 12, 2017 Abbreviations and acronymsCAS: Chemical Abstracts Service ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road RID: Regulation concerning the International Carriage of Dangerous Goods by Rail IMDG: International Maritime Dangerous Goods IATA: International Air Transportation Association TWA: Time Weighted Average STEL: Short term exposure limit LC50: Lethal Concentration 50% LD50: Lethal Dose 50% EC50: Effective Concentration 50% References IPCS - The International Chemical Safety Cards (ICSC), website: http://www.ilo.org/dyn/icsc/showcard.home HSDB - Hazardous Substances Data Bank, website: https://toxnet.nlm.nih.gov/newtoxnet/hsdb.htm IARC - International Agency for Research on Cancer, website: http://www.iarc.fr/ eChemPortal - The Global Portal to Information on Chemical Substances by OECD, website: http://www.echemportal.org/echemportal/index?pageID=0&request_locale=en CAMEO Chemicals, website: http://cameochemicals.noaa.gov/search/simple ChemIDplus, website: http://chem.sis.nlm.nih.gov/chemidplus/chemidlite.jsp ERG - Emergency Response Guidebook by U.S. Department of Transportation, website: http://www.phmsa.dot.gov/hazmat/library/erg Germany GESTIS-database on hazard substance, website: http://www.dguv.de/ifa/gestis/gestis-stoffdatenbank/index-2.jsp ECHA - European Chemicals Agency, website: https://echa.europa.eu/ Disclaimer: The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. We as supplier shall not be held liable for any damage resulting from handling or from contact with the above product. |
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