Although advances in industrial products have brought convenience to our lives, severe weather has increased the safety risks to industrial facilities. Considerable efforts have been made to develop high-performance superhydrophobic anti-icing coatings. Nevertheless, designing a functional coating with both anti-icing properties and self-deicing remains a major challenge. Here, we propose a design strategy to exploit a photothermal superhydrophobic multifunctional coating with excellent anti-icing and deicing properties based on MXene by high-temperature sintering and layer-by-layer coating. Specifically, poly(tetrafluoroethylene) (PTFE) particles provide low surface energy and binding effects. Room-temperature-vulcanized silicone rubber (RTV) enhances the dispersion of the composite particles and the adhesion of the functional coating to a glass substrate. Furthermore, the functional coatings constructed with MXene exhibit outstanding photothermal effects, imparting excellent superhydrophobicity (CA = 160.18°, SA = 1.8°) and efficient photothermal conversion (equilibrium temperature of 109.3 °C). An anti-icing/deicing test is simulated to confirm their efficient anti-icing/deicing performance in practical applications. Overall, the functional coatings designed in this work can be applied in real industrial facilities.